Order-to-disorder structural transformation of a coordination polymer and its influence on proton conduction.
نویسندگان
چکیده
We observed an ordered-to-disordered structural transformation in a Cu(2+) coordination polymer and investigated its influence on the proton conductivity. The transformation generated highly mobile proton carriers in the structure. The resulting material exhibited a conductivity greater than 10(-2) S cm(-1) at 130 °C. The structural transformation and the conduction mechanism were investigated by EXAFS, TPD-MS and NMR.
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عنوان ژورنال:
- Chemical communications
دوره 50 71 شماره
صفحات -
تاریخ انتشار 2014